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- Carvões portugueses: A revalorização moderna possível de um recurso geológico. O caso-de-estudo da Bacia Carbonífera do DouroPublication . Lemos de Sousa, M. J.; Rodrigues, Cristina; Diogo, Miguel Tato; Pinto de Jesus, A.; Mouraz Miranda, A.; Dinis, Maria Alzira Pimenta; Oliveira, Gisela; Chaminé, H.I.; Dinis da Gama, C.; Arrais, C.M.Na sequência de uma síntese sobre as formações datadas do Carbonífero presentes na Bacia Carbonífera do Douro e seu enquadramento geológico, os autores descrevem os estudos modernos, nomeadamente no domínio da estratigrafia efectuados na bacia. Após o fecho das minas de metantracites da bacia (1972 na área do Couto Mineiro de São Pedro da Cova e 1994 na área do Couto Mineiro do Pejão) desenvolveram-se outros importantes estudos, designadamente na área do Couto Mineiro do Pejão, relacionados com o fim da actividade mineira, nomeadamente nos domínios de subsidência mineira e afluxos de água e seus aspectos geológicos e hidrogeomecânicos, estudos estes de que se dá igualmente relato no presente trabalho. Por fim, apresenta-se o essencial do Projecto-Piloto COSEQ elaborado com vista a definir a possível revalorização, em termos modernos, das metantracites da Bacia Carbonífera do Douro como potencial meio de sequestração geológica de CO2. Com efeito, os carvões durienses constituem, hoje, um recurso geológico abandonado do ponto de vista mineiro tradicional.
- Workshop on "Energy, greenhouse gases and environment" proceedings, presentations and postersPublication . Lemos de Sousa, M. J.; Oliveira, Gisela; Rodrigues, Cristina; Dinis, Maria Alzira Pimenta; Diogo, Miguel Tato; Barros, Nelson
- O Carvão na ActualidadePublication . Lemos de Sousa, M. J.; Rodrigues, Cristina; Dinis, Maria Alzira Pimenta
- Effect of gas compressibility factor estimation in coal sorption isotherms accuracyPublication . Rodrigues, Cristina; da Silva, J.M. Machado; Dinis, Maria Alzira Pimenta; Lemos de Sousa, M. J.Compressibility factor (CF) is a key parameter in gas industry, regarding gas flow and storage in a gas reservoir. This study highlights the necessity to accurately estimate CF, affecting reservoir sorption capacity determination. The effect of the CF of N2, CH4 and CO2 in the coal porous structure was studied. Sorption isotherms showed no significant hysteresis regarding N2, due to gas inert behaviour. CH4 has a higher CF slope and the hysteresis behaviour is stronger than in N2. CO2 has no linear CF behaviour and besides relevant hysteresis, a distinct general trend between both curve shapes was identified, and the CO2 desorption curve intercepted the CO2 adsorption curve at 30x105 Pa. This is due to CO2 retention on coal porous structure, thanks to the great affinity between CO2 and the organic microporous structure, to pressures up to 6.9x105 Pa. The gas mixture showed a significant hysteresis due to its composition.
- Comparative study of the influence of minerals in gas sorption isotherms of three coals of similar rankPublication . Rodrigues, Cristina; Pinheiro, H. J.; Lemos de Sousa, M. J.; yesThis investigation compares the gas adsorption behaviour and capacity of three bituminous coals from South Africa, of similar rank, by assessing the characteristics of the raw coal, as well as the resulting float and sink fractions (at 1.80 cm3/g) obtained by density separation of crushed coal samples. Calculations were also made to obtain the raw coal gas storage capacity from the weighted contribution of both float and sink fractions results, thereby permitting comparison with the analysed results of the raw coal. The study demonstrated that the clean fraction of a coal has the highest capacity to retain gas in the sorbed state, followed by raw coal, and lastly the sink fraction, and re–confirmed previous investigations that showed minerals to be inhibitors of gas adsorption and retention.
- Sequestração geológica de dióxido de carbono: notas sobre o estado-da-artePublication . Lemos de Sousa, M. J.; Rodrigues, Cristina; Oliveira, GiselaApós uma breve introdução sobre os conceitos de (i) Alterações climáticas vs Alterações globais e de (ii) Gases de efeito de estufa, os autores apresentam o estado-da-arte sobre os principais problemas relacionados com a redução do dióxido de carbono e sua sequestração geológica. Por fim, fazem referência aos projectos existentes neste domínio no “Grupo de Investigação em Energia” do Centro de Investigação em Alterações Globais, Energia, Ambiente e Bioengenharia - CIAGEB da Universidade Fernando Pessoa. After a short introduction regarding concepts such as (i) Climate change vs Global changes, and (ii) Greenhouse gases effect, the authors present the state-of-the-art regarding problems related with Carbon dioxide abatement and geological sequestration. Finally, the authors refer to the current projects on this particular issue being developed by the “Energy Research Group” of the Global Change, Energy, Environment and Bioengineering RDID&D Unit – CIAGEB of Universidade Fernando Pessoa.
- Gas diffusion coefficient in coal: calculation of tangent slope accuracy through the inflection point determinationPublication . Rodrigues, Cristina; Dinis, Maria Alzira Pimenta; Lemos de Sousa, M. J.This investigation aims to develop an accurate method to calculate the tangent slope (b) - a fundamental parameter to calculate gas diffusion coefficients under different pressures - using inflection point determinations. The authors also studied the different tangent slope behaviours depending on the experimental gas sorption used. The single Langmuir model, for individual gases, and the extended Langmuir model, for multicomponent gas mixtures, were applied to fit experimental gas sorption isotherm data. Two coals were selected in order to minimize and/or avoid the maceral composition and vitrinite mean random reflectance effects. Samples were submitted to three different gas compositions, viz. 99.999% CH4; 99.999% CO2; and a gas mixture containing 74.99% CH4 + 19.99% CO2 + 5.02% N2. Results showed that the first and the second derivatives calculated to define the first inflection points represent exactly the final limit of tangent slopes.
- Gas content derivative data versus diffusion coefficientPublication . Rodrigues, Cristina; Dinis, Maria Alzira Pimenta; Lemos de Sousa, M. J.The study of the gas diffusion process has a main role in both Coalbed Methane (CBM) production and CO2 injection in geological sequestration projects. The accurate determination of gas diffusion coefficients in unconventional reservoirs such as coal seams, requires a consistent mathematical approach. The study of the gas diffusion process in coal seams was carried out using sorption isotherms. The Langmuir model for individual gases and the extended Langmuir model for multicomponent gas mixtures were applied to fit sorption isotherm data. “Gas content derivative data” and “gas content changes” emerged as crucial mathematical parameters to accurately study the gas diffusion process. The main goal of this paper is to define the degree of interaction between the gas content derivative data and the gas diffusion process. Experiments were performed on three samples selected from two different coals, which were submitted to three different gas compositions, viz 99.999% CH4; 99.999% CO2; and a gas mixture containing 74.99% CH4 + 19.99% CO2 + 5.02% N2, at 35ºC, and at pressures ranging from 0 up to 50 bar. Experimental results obtained from the three samples indicate that during adsorption/desorption processes, the diffusion coefficients increase and the gas content changes decrease when the pressure decreases, due to the sample saturation degrees and to the kinetic mechanisms increase. Additionally, the “gas content derivative data” scattering is slightly lower during the desorption process than during the adsorption process. These behaviors are clearly identified when using methane, but are even more evident when using CO2 and the gas mixture, due to the CO2 interaction with coal porous structure, which induces a considerable resistance to CO2 release. The results show that sample B (CH4 + CO2 + N2) displays higher diffusion coefficient values (this behaviour is mainly related to the presence of N2) than sample C (CH4) and than Sample A (CO2).
- The role of coal “cleat system” in Coalbed Methane Prospecting/Exploring: A new approachPublication . Rodrigues, Cristina; Laiginhas, C.; Fernandes, M.; Lemos de Sousa, M. J.The Coalbed Methane (CBM) generated by coal is located in coal pores and the drainage of the coalbed gas to the production well is made through the so-called "cleat system", i.e., the natural fracture network of coal. This justifies the classic method of CBM production by providing fracture-stimulation with fluids under pressure to open coal natural fractures. However, natural fracturing system of any coal is very complex, depending on coalification process and local and regional tectonics. Additionally, the cleat network cannot be inferred using conventional regional micro-tectonics studies. Therefore, what really matters is to know, in each case, the spatial orientation of the different classes of fracturing, ordered by connectivity frequencies, to make possible an orientated injection of fluids to open the cleat permitting higher amounts of gas release/drainage. In fact, the cleat family of highest connectivity frequency is the one that define the gas circulation network to the producing well, and consequently the most favorable one to be opened by fluids injected in the correct direction. The current investigation refers to a new and innovative proposal to develop a method for determining cleat family orientation in the space, ordered by cleat connectivity frequency. This new semi-automatic method is based in the study of "cleat characteristics" by image analysis in orientated core samples of boreholes for CBM prospection/exploration. The information from image analysis is studied by statistical CCT ("coal-core tectonics") methodology and subsequently combined with Geographic Information System, thus referring to location of the real case under study.
- Tecnologias CAC e Inquéritos de Percepção da Opinião Pública sobre “O papel da Captação e do Armazenamento/Sequestração de Dióxido de Carbono no Futuro da Energia na Europa”:O caso-de-estudo da Comunidade Fernando Pessoa: CCS Technologies and Inquiries into Public Perception on “The Role of Carbon Dioxide Capture and Storage in Europe’s Energy Future“ - the case-study of University Fernando Pessoa CommunityPublication . Oliveira, Gisela; Silva, Pedro Nuno; Maia, Rui Leandro; Rodrigues, Cristina; Diogo, Miguel Tato; Dinis, Maria Alzira Pimenta; Ribeiro, Nuno Magalhães; Lemos de Sousa, M. J.O carvão e outros combustíveis fósseis, continuarão a ser, por décadas, a principal matéria-prima energética para as Centrais Térmicas, não obstante os esforços para, dentro do possível, substituir os combustíveis fósseis por fontes de energia renovável.Tal como está, hoje, bem documentado, a produção de gases com efeito estufa (GEE), designadamente CO2, resulta da combustão dos ditos combustíveis fósseis, sendo que se espera ser possível mitigar substancialmente a emissão de tais gases com a aplicação das chamadas Tecnologias Limpas do Carvão.Há, pois, necessidade de promover o abatimento do CO2 através de Tecnologias de Emissão Zero ou Tecnologias Livres de Carbono, incluindo designadamente a Captura, o Transporte e a Sequestração geológica de CO2 correspondentes ao que é costume designar por Tecnologias CAC (Captação e Armazenamento de Carbono). De facto, tais tecnologias e, designadamente, o armazenamento geológico de CO2 são as únicas que, no estado actual do conhecimento, são capazes de permitir que se cumpram as metas do ambicioso programa da EU para a energia e o ambiente conhecido por “20 20 para 2020” em conjugação com os aspectos económicos das directivas relativas ao Comércio Europeu de Licenças de Emissão – CELE (Directivas 2003/87/EC, 2004/101/EC e 2009/29/EC).A importância do tema está, aliás, bem demonstrada com o facto da Comissão Europeia ter formalmente admitido que as metas supracitadas serão impossíveis de atingir sem Sequestração Geológica de CO2. Esta é, pois, uma das razões de ter sido recentemente publicada a Directiva Europeia 2009/31/EC de 23 de Abril de 2009 expressamente dedicada ao tema do Armazenamento Geológico de CO2.Ora, a questão do armazenamento geológico de CO2 implica, para além das Tecnologias CAC acima mencionadas e da sua viabilização em termos tanto técnicos como económicos, ou seja, neste último aspecto, competitiva com o sistema CELE, também o conhecimento, da percepção pública sobre o assunto. Isto é, a praticabilidade das Tecnologias CAC implica que se conheça a opinião pública sobre o tema e, naturalmente, que face a esta realidade se prestem os esclarecimentos necessários como, aliás, é reconhecido na própria Directiva Europeia 2009/31/EC.Dado que a Fundação Fernando Pessoa / Universidade Fernando Pessoa através do seu Centro de Investigação em Alterações Globais, Energia, Ambiente e Bioengenharia – CIAGEB tem ultimado um Projecto de Engenharia relativo à Sequestração Geológica de CO2 nos Carvões (Metantracites) da Bacia Carbonífera do Douro – o Projecto COSEQ, preocupou-se naturalmente, desde o início, com o lançamento de inquéritos de percepção da opinião pública sobre o assunto.Tal implicou, nesta fase, a tradução para português e o lançamento do inquérito europeu ACCSEPT que não tinha sido ainda formalmente lançado de forma generalizada entre nós. Antes, porém, de lançar publicamente tal inquérito – o que está actualmente já em curso – resolveu-se testar o método de lançamento, a recolha de dados e o seu tratamento com uma amostra correspondente ao que se designou por Comunidade Fernando Pessoa, i.e. o conjunto de docentes, discentes, funcionários e outras pessoas relacionadas com a Universidade Fernando Pessoa (cerca de 5000 individualidades).Este trabalho diz, precisamente, respeito à preparação, lançamento e análise dos resultados do dito inquérito Europeu ACCSEPT a nível da Comunidade Fernando Pessoa. Foram recebidas 525 respostas representando 10,5% da amostra. A análise de resultados foi sistematicamente comparada com os obtidos nos outros países europeus, através do projecto ACCSEPT e, bem assim, com os resultados obtidos num inquérito homólogo lançado no Brasil. The use of coal, and other fossil fuels, will remain for decades as the main source of energy for power generation, despite the important efforts made to replace, as far as possible, fossil fuels with renewable power sources.As is well documented, the production of Greenhouse Gases (GHG), mainly CO2, arises primarily from the combustion of fossil fuels. The increasing application of Clean Coal Technologies-CCTs, is expected to mitigate substantially against the emission of such gases.There is consequently a need to promote the CO2 abatement through Zero Emission (Carbon Free) Technologies - ZETs, which includes CO2 capture, transport and geological storage, i.e. the so-called CCS (Carbon, Capture and Storage) technologies. In fact, these technologies are the only ones that are presently able to conform to the ambitious EU targets set out under the “20 20 by 2020” EU energy and environment programme, jointly with the economic aspects of the EU Directives 2003/87/EC, 2004/101/EC and 2009/29/EC concerned with the Greenhouse Gas Emissions Allowance Trading Scheme – ETS scheme. The European Commission formal admission that the referred targets will be impossible to reach without the implementation and contribution of geological storage clearly demonstrate the importance of this particular issue, and for this reason the EC Directive 2009/31/EC of April 23, 2009 on Geological Storage of CO2 was recently published.In considering the technical and economical viabilities of CCS technologies, the latter in competition with the ETS scheme, it is believed that public perception will dictate the success of the development and implementation of CO2 geological storage at a large industrial level. This means that, in order to successfully implement CCS technologies, not only must public opinion be taken into consideration but objective information must also be provided to the public in order to raise subject awareness, as recognized in the referred Directive 2009/31/EC.In this context, the Fernando Pessoa Foundation / University Fernando Pessoa, through its CIAGEB (Global Change, Energy, Environment and Bioengineering) RDID&D Unit, is the sponsor of an Engineering Project for the Geological Sequestration of CO2 in Douro Coalfield Meta-anthracites - the COSEQ Project, and is therefore also engaged in public perception surveys with regards to CCS technologies.At this stage, the original European ACCSEPT inquiry was translated to Portuguese and submitted only to the “Fernando Pessoa Community” - comprising university lecturers, students, other employees, as well as, former students and persons that have a professional or academic relationship with the university (c. 5000 individuals). The results obtained from this first inquiry will be used to improve the survey informatics system in terms of communication, database, and data treatment prior to resubmission of the inquiry to the Portuguese public at large.The present publication summarizes the process and the results obtained from the ACCSEPT survey distributed to the “Fernando Pessoa Community”. 525 replies, representing 10.5% of the sample, have been received and analysed. The assessment of the results was systematically compared with those obtained from other European Countries, as reported by the ACCSEPT inquiry, as well as with those from an identical inquiry launched in Brazil.
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