Loading...
6 results
Search Results
Now showing 1 - 6 of 6
- Improving air quality in Lisbon: modelling emission abatement scenariosPublication . Monjardino, J.; Barros, Nelson; Ferreira, F.; Tente, H.; Fontes, Tânia; Pereira, P.; Manso, M. ConceiçãoLisbon is one of the European cities where NO2 and PM10 legal limit values are still exceeded, leading to an Air Quality Plan applicable up to 2020. The developed work combined a detailed emission inventory, monitoring data, and modelling in order to assess if the proposed emission abatement scenarios, focused on the road transport sector, were able to tackle exceedances. A maximum decrease of 14% for PM10 concentrations was achieved, and of 21% for NO2, providing compliance. PM10 smallest reduction is related with higher weight of regional background sources, while for NO2 local traffic has more influence on concentrations.
- Learning from 24 years of ozone data in PortugalPublication . Barros, Nelson; Silva, M.P.; Fontes, Tânia; Manso, M. Conceição; Carvalho, Ana CristinaOzone (O3) is a secondary pollutant mainly produced in the troposphere by photochemical reactions with high impact on human health. In this work hourly average O3 concentrations from the Portuguese air quality network collected during 24 years (1988–2011) were analysed. The background time series were assessed by environment type (urban, suburban and rural) and considering several criteria: the annual mean O3 concentration, the Directive 2008/50/EC O3 long-term objective and the 2005 WHO Guideline for protection of human health and, finally, the hourly information threshold exceedances. The trend of annual mean O3 concentration data and the maximum daily eight-hour mean ozone concentration data were both annually compared using an one-way ANOVA followed by a Tamhane post-hoc comparison test. In both series, although of an instable trend, a tendency for an increase of the mean O3 concentrations was found. On the other hand, after 2006, for all stations types, the normalized number of exceedances for public O3 information are significantly decreasing (p<0.05). In this paper, the O3 trend will be analyzed and discussed, contributing to improve knowledge of long time series of O3 concentrations in Portugal.
- Environmental and biological monitoring of benzene, toluene, ethylbenzene and xylene (BTEX) exposure in residents living near gas stationsPublication . Barros, Nelson; Carvalho, Márcia; Silva, Cláudia; Fontes, Tânia; Prata, Joana C.; Sousa, André; Manso, M. ConceiçãoThe volatile organic compounds benzene, toluene, ethylbenzene, and xylene (BTEX) are emitted into the atmosphere at gas stations (GS) leading to chronic exposure of nearby residents, which raises public health concerns. This study aimes at determining the contribution of GS emissions to BTEX exposure in nearby residents. Three Control and Exposed areas to BTEX emissions from GS were defined in a medium-sized European city (Porto, Portugal). BTEX atmospheric levels were determined in Control and Exposed areas using passive samplers deployed outdoors (n = 48) and indoors (n = 36), and human exposure was estimated for 119 non-smoking residents using the first urine of the day. Results showed that median BTEX outdoor and indoor concentrations were significantly higher for Exposed than Control areas, with exception of ethylbenzene and xylene indoor concentrations, where no marked differences were found. Comparison of urinary concentrations between Exposed and Control residents demonstrated no significant differences for benzene and ethylbenzene, whereas levels of toluene and xylene were significantly higher in Exposed residents. No marked correlation was obtained between atmospheric BTEX concentrations and urinary concentrations. Data indicate the potential impact on air quality of BTEX emissions from GS, which confirms the importance of these findings in urban planning in order to minimize the impact on health and well-being of surrounding populations.
- Exposure to BTEX in buses: the influence of vehicle fuel typePublication . Fontes, Tânia; Manso, M. Conceição; Prata, Joana C; Carvalho, Márcia; Silva, Cláudia; Barros, NelsonDiesel-fueled buses have been replaced by Compressed Natural Gas (CNG) to minimize the high level of emissions in urban areas. However, differences in indoor exposure levels to Benzene, Toluene, Ethylbenzene and Xylene (BTEX) in those vehicles have not been investigated so far. The primary aim of this study was to determine if passengers are exposed to different BTEX levels when using buses powered by CNG or by diesel, and further explore if indoor levels are influenced by external air quality. For this purpose, BTEX air concentrations were measured in bus cabins (CNG and diesel), parking stations and in a background urban area using passive air samplers. Results showed that BTEX concentrations inside vehicles were higher than outside, but no significant differences were found between buses powered by CNG or by diesel. In CNG vehicles, high and significant positive correlation was found between benzene and the number of journeys in the same route (rs ¼ 0.786, p < 0.05), vehicle operating time (rs ¼ 0.738, p < 0.05), exposure time (rs ¼ 0.714, p < 0.05) and exposure index (rs ¼ 0.738, p < 0.05), but this was not observed for diesel vehicles. Benzene in bus cabins was found to be significantly below reference value for human health protection. However, excepting p-xylene, all other aromatic pollutants have a mean concentration significantly above the lowest effect level (p 0.002 for all comparisons). Additionally, higher BTEX levels in cabin buses than in outdoor air suggest the presence of other emission sources in indoor cabins. These findings emphasize the need for further studies to fully characterize indoor emission sources in order to minimize the negative impact of BTEX exposure to human health.
- Analysis of the effectiveness of the NEC Directive on the tropospheric ozone levels in PortugalPublication . Barros, Nelson; Fontes, Tânia; Silva, M.P.; Manso, M. Conceição; Carvalho, A.C.The National Emission Ceilings Directive 2001/81/CE (NEC Directive) was adopted in the European Community in 2001 and went through a revision process in 2005. One of its main objectives is to improve the protection of the environment and human health against the risks of adverse effects from ground-level ozone, moving towards the long-term objective of not exceeding critical levels proved to effectively protect the populations and ecosystems. Considering such objectives, national emission ceilings were established imposing the years 2010 and 2020 as benchmarks. Ten years later, what was the effectiveness of this Directive concerning the control of tropospheric ozone levels in Portugal? In order to answer the previous question, annual ozone precursors' emissions (NOx, NMVOC) and annual atmospheric concentrations (NOx and O3) were analyzed between 1990 and 2011. The background concentrations were assessed in each environment type of air quality station (urban, suburban and rural) through their annual mean ozone concentration and the hourly information threshold exceedances (episodic peak levels). To evaluate the statistical differences in the inter-annual episodic peak levels, a Peak Ozone Index (POIx) was defined and calculated. The results show that, despite the achievement on the emissions NEC Directive goals, associated to the reduction of ozone precursors' emissions, and the decrease of ozone episodic peak levels, the mean tropospheric ozone concentrations significantly increased between 2003 and 2007 (p < 0.05) although the number of exceedances to the information threshold (180 mg m3 ) has decreased. During the period of 1990e2000, before the implementation of the NEC Directive, the mean ozone values were 25% lower in rural stations, 26% in urban stations and 12% in suburban stations, demonstrating that the NEC policy based on NOx and NMVOCs emissions reduction does not lead to an effective overall reduction of ozone concentrations considering the reduction on these pollutants independently. Indeed, the mesoscale ozone production and/or the long range advection may play also an important role as the analysis of Mace Head ozone concentrations suggests. Above all, and due to its non-linear interactions in the ozone chemical balance, the NEC directive should impose emissions' reduction respecting the NOx/NMVOC ratio instead of consider it as a mere guideline value. The mesoscale photochemical ozone production should be carefully analyzed under the new policies, namely in coastal countries like Portugal where the mesoscale circulations play a crucial role in this type of phenomena.
- How wide should be the adjacent area to an urban motorway to prevent potential health impacts from traffic emissions?Publication . Barros, Nelson; Fontes, Tânia; Silva, M.P.; Manso, M. ConceiçãoIn recent years, several studies show that people who live, work or attend school near the main roadways have an increased incidence and severity of health problems that may be related with traffic emissions of air pollutants. The concentrations of near-road atmospheric pollutants vary depending on traffic patterns, environmental conditions, topography and the presence of roadside structures. In this study, the vertical and horizontal variation of nitrogen dioxide (NO2) and benzene (C6H6) concentration along a major city ring motorway were analysed. The main goal of this study is to try to establish a distance from this urban motorway considered ‘‘safe’’ concerning the air pollutants human heath limit values and to study the influence of the different forcing factors of the near road air pollutants transport and dispersion. Statistic significant differences (p = 0.001, Kruskal–Wallis test) were observed between sub-domains for NO2 representing different conditions of traffic emission and pollutants dispersion, but not for C6H6 (p = 0.335). Results also suggest significant lower concentrations recorded at 100 m away from roadway than at the roadside for all campaigns (p < 0.016 (NO2) and p < 0.036 (C6H6), Mann–Whitney test). In order to have a ‘‘safe’’ life in homes located near motorways, the outdoor concentrations of NO2 must not exceed 44–60.0 lg m3 and C6H6 must not exceed 1.4– 3.3 lg m3 . However, at 100 m away from roadway, 81.8% of NO2 receptors exceed the annual limit value of human health protection (40 lg m3 ) and at the roadside this value goes up to 95.5%. These findings suggest that the safe distance to an urban motorway roadside should be more at least 100 m. This distance should be further studied before being used as a reference to develop articulated urban mobility and planning policies.