Browsing by Author "Silva, M.P."
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- Analysis of the effectiveness of the NEC Directive on the tropospheric ozone levels in PortugalPublication . Barros, Nelson; Fontes, Tânia; Silva, M.P.; Manso, M. Conceição; Carvalho, A.C.The National Emission Ceilings Directive 2001/81/CE (NEC Directive) was adopted in the European Community in 2001 and went through a revision process in 2005. One of its main objectives is to improve the protection of the environment and human health against the risks of adverse effects from ground-level ozone, moving towards the long-term objective of not exceeding critical levels proved to effectively protect the populations and ecosystems. Considering such objectives, national emission ceilings were established imposing the years 2010 and 2020 as benchmarks. Ten years later, what was the effectiveness of this Directive concerning the control of tropospheric ozone levels in Portugal? In order to answer the previous question, annual ozone precursors' emissions (NOx, NMVOC) and annual atmospheric concentrations (NOx and O3) were analyzed between 1990 and 2011. The background concentrations were assessed in each environment type of air quality station (urban, suburban and rural) through their annual mean ozone concentration and the hourly information threshold exceedances (episodic peak levels). To evaluate the statistical differences in the inter-annual episodic peak levels, a Peak Ozone Index (POIx) was defined and calculated. The results show that, despite the achievement on the emissions NEC Directive goals, associated to the reduction of ozone precursors' emissions, and the decrease of ozone episodic peak levels, the mean tropospheric ozone concentrations significantly increased between 2003 and 2007 (p < 0.05) although the number of exceedances to the information threshold (180 mg m3 ) has decreased. During the period of 1990e2000, before the implementation of the NEC Directive, the mean ozone values were 25% lower in rural stations, 26% in urban stations and 12% in suburban stations, demonstrating that the NEC policy based on NOx and NMVOCs emissions reduction does not lead to an effective overall reduction of ozone concentrations considering the reduction on these pollutants independently. Indeed, the mesoscale ozone production and/or the long range advection may play also an important role as the analysis of Mace Head ozone concentrations suggests. Above all, and due to its non-linear interactions in the ozone chemical balance, the NEC directive should impose emissions' reduction respecting the NOx/NMVOC ratio instead of consider it as a mere guideline value. The mesoscale photochemical ozone production should be carefully analyzed under the new policies, namely in coastal countries like Portugal where the mesoscale circulations play a crucial role in this type of phenomena.
- How wide should be the adjacent area to an urban motorway to prevent potential health impacts from traffic emissions?Publication . Barros, Nelson; Fontes, Tânia; Silva, M.P.; Manso, M. ConceiçãoIn recent years, several studies show that people who live, work or attend school near the main roadways have an increased incidence and severity of health problems that may be related with traffic emissions of air pollutants. The concentrations of near-road atmospheric pollutants vary depending on traffic patterns, environmental conditions, topography and the presence of roadside structures. In this study, the vertical and horizontal variation of nitrogen dioxide (NO2) and benzene (C6H6) concentration along a major city ring motorway were analysed. The main goal of this study is to try to establish a distance from this urban motorway considered ‘‘safe’’ concerning the air pollutants human heath limit values and to study the influence of the different forcing factors of the near road air pollutants transport and dispersion. Statistic significant differences (p = 0.001, Kruskal–Wallis test) were observed between sub-domains for NO2 representing different conditions of traffic emission and pollutants dispersion, but not for C6H6 (p = 0.335). Results also suggest significant lower concentrations recorded at 100 m away from roadway than at the roadside for all campaigns (p < 0.016 (NO2) and p < 0.036 (C6H6), Mann–Whitney test). In order to have a ‘‘safe’’ life in homes located near motorways, the outdoor concentrations of NO2 must not exceed 44–60.0 lg m3 and C6H6 must not exceed 1.4– 3.3 lg m3 . However, at 100 m away from roadway, 81.8% of NO2 receptors exceed the annual limit value of human health protection (40 lg m3 ) and at the roadside this value goes up to 95.5%. These findings suggest that the safe distance to an urban motorway roadside should be more at least 100 m. This distance should be further studied before being used as a reference to develop articulated urban mobility and planning policies.
- Learning from 24 years of ozone data in PortugalPublication . Barros, Nelson; Silva, M.P.; Fontes, Tânia; Manso, M. Conceição; Carvalho, Ana CristinaOzone (O3) is a secondary pollutant mainly produced in the troposphere by photochemical reactions with high impact on human health. In this work hourly average O3 concentrations from the Portuguese air quality network collected during 24 years (1988–2011) were analysed. The background time series were assessed by environment type (urban, suburban and rural) and considering several criteria: the annual mean O3 concentration, the Directive 2008/50/EC O3 long-term objective and the 2005 WHO Guideline for protection of human health and, finally, the hourly information threshold exceedances. The trend of annual mean O3 concentration data and the maximum daily eight-hour mean ozone concentration data were both annually compared using an one-way ANOVA followed by a Tamhane post-hoc comparison test. In both series, although of an instable trend, a tendency for an increase of the mean O3 concentrations was found. On the other hand, after 2006, for all stations types, the normalized number of exceedances for public O3 information are significantly decreasing (p<0.05). In this paper, the O3 trend will be analyzed and discussed, contributing to improve knowledge of long time series of O3 concentrations in Portugal.